What Is the Difference Between p-Xylene and o-Xylene?
1. Structural Differences
p-Xylene and o-xylene are both isomers of dimethylbenzene, with the chemical formula C₈H₁₀. Their main structural difference lies in the positions of the two methyl groups attached to the benzene ring.
For o-xylene (1,2-dimethylbenzene), the two methyl groups are on adjacent carbon atoms of the benzene ring.
For p-xylene (1,4-dimethylbenzene), the two methyl groups are on opposite carbon atoms of the benzene ring.
2. Differences in Physical Properties
| Physical Property | p-Xylene (P-Xylene) | o-Xylene (O-Xylene) |
|---|---|---|
| Chemical Formula | C₈H₁₀ | C₈H₁₀ |
| CAS Number | 106-42-3 | 95-47-6 |
| Molecular Weight | 106.16 g/mol | 106.16 g/mol |
| Appearance | Colorless, transparent liquid | Colorless, transparent liquid |
| Odor | Aromatic hydrocarbon odor | Aromatic hydrocarbon odor |
| Melting Point | ≈ 13.2 °C | ≈ -25 °C |
| Boiling Point | ≈ 138.4 °C | ≈ 144.4 °C |
| Density (20 °C) | ~0.861 g/cm³ | ~0.880 g/cm³ |
| Vapor Pressure (25 °C) | Lower | Higher |
| Solubility in Water | Insoluble | Insoluble |
| Solubility in Organic Solvents | Miscible | Miscible |
| Flash Point (Closed Cup) | ~27 °C | ~30 °C |
| State at Room Temperature | Liquid (may crystallize in cold conditions) | Liquid |
3. Differences in Applications
p-Xylene is mainly used to make terephthalic acid, which is an important material for PET plastic bottles and polyester fibers.
O-xylene is mainly used in manufacturing phthalic anhydride, and it is produced during petroleum cracking.
Understanding the physical differences between p-Xylene and o-Xylene helps buyers choose the right material for PTA production, solvent applications, coatings, and chemical synthesis, Looking for a reliable p-Xylene and o-Xylene supplier? Contact us for bulk supply, COA, SDS and competitive pricing.
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