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What Is the Difference Between p-Xylene and o-Xylene?

Jan 29, 2026 Leave a message

What Is the Difference Between p-Xylene and o-Xylene?

 

1. Structural Differences

p-Xylene and o-xylene are both isomers of dimethylbenzene, with the chemical formula C₈H₁₀. Their main structural difference lies in the positions of the two methyl groups attached to the benzene ring.

For o-xylene (1,2-dimethylbenzene), the two methyl groups are on adjacent carbon atoms of the benzene ring.

For p-xylene (1,4-dimethylbenzene), the two methyl groups are on opposite carbon atoms of the benzene ring.

 

2. Differences in Physical Properties

Physical Property p-Xylene (P-Xylene) o-Xylene (O-Xylene)
Chemical Formula C₈H₁₀ C₈H₁₀
CAS Number 106-42-3 95-47-6
Molecular Weight 106.16 g/mol 106.16 g/mol
Appearance Colorless, transparent liquid Colorless, transparent liquid
Odor Aromatic hydrocarbon odor Aromatic hydrocarbon odor
Melting Point ≈ 13.2 °C ≈ -25 °C
Boiling Point ≈ 138.4 °C ≈ 144.4 °C
Density (20 °C) ~0.861 g/cm³ ~0.880 g/cm³
Vapor Pressure (25 °C) Lower Higher
Solubility in Water Insoluble Insoluble
Solubility in Organic Solvents Miscible Miscible
Flash Point (Closed Cup) ~27 °C ~30 °C
State at Room Temperature Liquid (may crystallize in cold conditions) Liquid

 

3. Differences in Applications

p-Xylene is mainly used to make terephthalic acid, which is an important material for PET plastic bottles and polyester fibers.
O-xylene is mainly used in manufacturing phthalic anhydride, and it is produced during petroleum cracking.

 

Understanding the physical differences between p-Xylene and o-Xylene helps buyers choose the right material for PTA production, solvent applications, coatings, and chemical synthesis, Looking for a reliable p-Xylene and o-Xylene supplier? Contact us for bulk supply, COA, SDS and competitive pricing.

 

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