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CAS 79-01-6 Trichloroethylene: Structure, Uses, Key Properties

Mar 30, 2026 Leave a message

CAS No 79-01-6 Trichloroethylene (TCE) is a colorless, non-flammable liquid widely used as an industrial solvent, degreaser, and chemical intermediate.

 

Trichloroethene with a molecular formula of C2HCl3 is a transparent, mobile, colourless liquid with an ether-like odour.

  • Density -1.46g/cm3
  • Molecular weight-131.4 g/mol
  • Boiling point- 87.2 C
  • Melting point- -73C

 

Molecular Structure of TCE chemical

Chemical Formula: C₂HCl₃

Structure: Trichlorinated ethylene

  • Two carbon atoms double-bonded (C=C)
  • Three chlorine atoms attached to the carbons

 

Structure Of TCE 

 

key Physical and Chemical Properties of Trichloroethylene TCE

Molecular Formula C₂HCl₃
Molecular Weight 131.39 g/mol
Boiling Point 86.7°C
Density 1.46 g/mL
Solubility Slightly soluble in water, miscible with organic solvents
Flash Point Non-flammable
Appearance Colorless liquid

 

The Chemical Reaction of Trichloroethylene

4 C2HCl3+ 9 O2 → 8 CO2 + 2 H2O + 6 Cl2

 

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Applications of Trichloroethylene TCE Solvent

Industrial and Historical Uses

  1. Metal Degreasing: The primary use (>80%–90%) of Trichloroethylene solvent is for vapor degreasing of metal parts to remove grease, oils, and contaminants in the automotive and aerospace industries.
  2. Chemical Intermediate: Used as a feedstock in the production of hydrofluorocarbon (HFC) refrigerants, such as HFC-134a.
  3. Other Uses: Historically TCE is used as an anesthetic, a dry cleaning solvent (spot cleaner), in textile processing, and as an extraction solvent for fats, oils, and caffeine (decaffeination)

 

Health and Toxicity

Health Risks: Prolonged exposure may affect liver, kidney, and nervous system

Environmental Impact: Can contaminate soil and groundwater; persistent in the environment

Regulations: Controlled in EU, US, and many other regions; mainly industrial use now

 

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Safety & Handling information

Due to its classification by health agencies, Trichloroethylene TCE must be handled with extreme care. The U.S. Environmental Protection Agency (EPA) has identified significant health risks associated with TCE exposure, classifying it as carcinogenic to humans.

  1. Ventilation is Paramount: Always use TCE solvent in a well-ventilated area, preferably with local exhaust ventilation (LEV) systems to capture vapors at the source.
  2. Personal Protective Equipment (PPE): Chemical-resistant gloves, splash goggles, and a NIOSH-approved respirator with an organic vapor cartridge are essential.
  3. Storage and Disposal: Store in a cool, dry, well-ventilated area away from direct sunlight and incompatible materials. Dispose of TCE and contaminated materials as hazardous waste according to all federal, state, and local regulations.

 

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