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What are the boiling point and density of acetic acid CAS 64-19-7?

Jun 17, 2026 Leave a message

Michael Zhang
Michael Zhang
Michael Zhang is a chemical industry specialist with experience in industrial solvents, petrochemicals, and global chemical supply chains. He researches chemical properties, applications, safety, providing technical content for purchasers.

Quick Answer

The density of pure glacial acetic acid (CAS 64-19-7)is 1.0492 g/cm³ at 20°C (68°F), while its normal boiling point is 117.9°C (244.2°F) at standard atmospheric pressure (101.325 kPa).

 

Glacial Acetic Acid/Acetic Acid with chemical formula CH3COOH is a monocarboxylic acid with one "COOH" group. It's an anhydrous, clear, colourless liquid having a pungent smell. Acetic acid is also known as ethanoic acid, ethylic acid, vinegar acid, and methane carboxylic acid. In the diluted form. next to formic acid, acetic acid is the simplest carboxyl group. Acetic acid uses are umpteen, and it is used across several industries.

 

What Is the Density of Acetic Acid?

The density of pure glacial acetic acid (CAS 64-19-7) is 1.049 g/cm³ at 20°C (68°F), equivalent to 1049 kg/m³ or 8.75 lb/gal. At 25°C (77°F), the density decreases slightly to 1.044 g/cm³ due to thermal expansion.

 

Density is a critical physical property for:

  • Accurate volume-to-mass conversions in industrial formulations
  • Storage tank capacity calculations
  • Transportation logistics and weight compliance
  • Quality control and purity verification
  • Process engineering and reaction stoichiometry

 

Acetic Acid Density vs Temperature:

Temperature (°C) Density (g/cm³) Density (kg/m³)
0 1.0716 1071.6
10 1.0605 1060.5
20 1.0492 1049.2
25 1.0437 1043.7
30 1.0382 1038.2
40 1.0271 1027.1
50 1.0157 1015.7
60 1.0040 1004.0
80 0.9796 979.6
100 0.9543 954.3
117.9 (Boiling Point) 0.9320 932.0

 

What Is the Boiling Point of Acetic Acid?

The Boiling Point of Acetic acid is 117.9 °C. At this temperature, liquid acetic acid will convert to a gaseous state under normal pressure.

Boiling point is very important in industrial processes such as chemical distillation, solvent recovery, purification, reaction temperature control, as well as storage and transportation planning. Glacial acetic acid has a relatively high boiling point compared with many other solvents, so it remains stable in most production environments.

 

Acetic Acid Boiling Point at Different Pressures:

Pressure (kPa) Boiling Point (°C) Boiling Point (°F)
101.325 117.9 244.2
80 110.5 230.9
50 98.5 209.3
20 78.5 173.3
10 62.8 145.0
5 48.8 119.8
1 17.5 63.5

 

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Complete Physical Properties of Acetic Acid (CAS 64-19-7)

Property Value
Chemical Name Acetic Acid
Synonym Ethanoic Acid
CAS Number 64-19-7
Molecular Formula CH₃COOH / C₂H₄O₂
Molecular Weight 60.05 g/mol
Appearance Clear Colorless Liquid
Boiling Point 117.9°C
Melting Point 16.6°C
Density (20°C) 1.0492 g/cm³
Density (25°C) 1.0437 g/cm³
Flash Point (Closed Cup) 39°C
Autoignition Temperature 463°C
Vapor Pressure (20°C) Approx. 1.5–1.6 kPa
Vapor Density (Air = 1) 2.07
Refractive Index (20°C) 1.3716
Viscosity (20°C) 1.22 mPa·s
pKa (25°C) 4.756
Solubility in Water Completely Miscible
Dielectric Constant (20°C) 6.15

 

Learn more about acetic acid chemical properties and specifications to match your industry. Click here!

 

What Is Acetic acid solvent Used For?

Industry and Manufacturing

The largest industrial use of acetic acid is in the production of vinyl acetate, a fundamental ingredient in paints, adhesives, and coatings. Acetic acid is also used to produce acetic anhydride, which is used in the production of synthetic fibers and film materials.

 

Pharmaceuticals and Medical

In the pharmaceutical field, high-purity acetic acid is used in the production of vitamins, antibiotics, and certain hormones. Diluted acetic acid solutions are used to treat ear infections.

 

Food Industry

As a food additive (labeled E260), acetic acid acts as a preservative and helps control acidity. It is found in pickles, condiments, and many processed foods.

 

Household Cleaning

White vinegar, a diluted solution of acetic acid, is a common household cleaner. It can remove mineral deposits, degrease, and disinfect a variety of surfaces.

 

Textiles and Leather

In fabric production, acetic acid helps regulate pH during the dyeing process, allowing color to penetrate the material more evenly.

 

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Frequently Asked Questions (FAQ)

Q: Why is acetic acid's boiling point so high compared to other organic solvents?

A: Acetic acid forms stable dimers through hydrogen bonding between two molecules. This dimerization effectively doubles the molecular weight in the liquid phase, requiring significantly higher temperatures to achieve vaporization. The boiling point of 117.9°C is much higher than ethanol (78.4°C) or acetone (56°C) with similar molecular weights.

 

Q: How does glacial acetic acid (GAA) differ from regular acetic acid?

A: "Glacial" refers to 99.5%+ pure anhydrous acetic acid. It gets its name because it solidifies into ice-like crystals at 16.6°C (61.9°F), just below room temperature. Technical-grade acetic acid typically ranges from 80-99% purity, while vinegar contains only 4-8% acetic acid in water.

 

Q: What is the density of 99% glacial acetic acid CAS 64-19-7?

A: 99% glacial acetic acid has a density of approximately 1.050 g/cm³ at 20°C. The difference between 99% and 100% purity is minimal (less than 0.1%) because water and acetic acid have very similar densities at this concentration range.

 

Q: Is acetic acid chemical heavier than water?

A: Yes, pure acetic acid (1.049 g/cm³) is approximately 5% denser than water (1.000 g/cm³ at 4°C). However, when mixed with water, the density first increases to a maximum at ~79% concentration before decreasing as dilution continues.

 

 

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