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How to make vinyl acetate monomer?

Dec 28, 2025 Leave a message

CAS 108-05-4 Vinyl acetate monomer (VAM) is a clear, colourless, and flammable liquid with a strong, pungent odour. It is soluble in most organic solvents, including chlorinated solvents, but is insoluble in water. VAM is primarily used as a key building block in the production of polymers such as polyvinyl acetate and polyvinyl alcohol, which are essential in adhesives, coatings, films, and paints.

 

How to make vinyl acetate monomer?

The dominant industrial production method is the vapor-phase reaction of ethylene, acetic acid, and oxygen over a noble metal catalyst (like palladium and gold on a support).


Simplified Reaction:
CH₂=CH₂ (Ethylene) + CH₃COOH (Acetic Acid) + ½ O₂ (Oxygen) → CH₃COOCH=CH₂ (Vinyl Acetate) + H₂O (Water)

 

This process is known as the ethylene method or Monsanto/Bayer process and accounts for most global production. An older method (the acetylene method) reacted acetylene with acetic acid.

 

 

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Acetic acid ethenyl ester (CAS 108-05-4)

 

Vinyl acetate monomer (VAM) Liquid

 

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